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January 31, 2010

The Geological Prize Called Haiti ?

8:24 pm

Somewhat to my surprise my most highly read article of the past week was an off-the-cuff pointer to some tinfoil about oil in Haiti. F William Engdahl (one time peak oil theorist and now vociferous anti-peak oil and anti-global warming theorist) has taken to the story like a duck to water, floating his now familiar theory about abiotic oil and suppression of oil production – The Fateful Geological Prize Called Haiti. I guess time will tell if Haiti does have any oil or if this is all just some colourful theorising from the fringes.

A President becomes UN Special Envoy to earthquake-stricken Haiti.

A born-again neo-conservative US business wheeler-dealer preacher claims Haitians are condemned for making a literal ‘pact with the Devil.’

Venezuelan, Nicaraguan, Bolivian, French and Swiss rescue organizations accuse the US military of refusing landing rights to planes bearing necessary medicines and urgently needed potable water to the millions of Haitians stricken, injured and homeless.

Behind the smoke, rubble and unending drama of human tragedy in the hapless Caribbean country, a drama is in full play for control of what geophysicists believe may be one of the world’s richest zones for hydrocarbons-oil and gas outside the Middle East, possibly orders of magnitude greater than that of nearby Venezuela.

Haiti, and the larger island of Hispaniola of which it is a part, has the geological fate that it straddles one of the world’s most active geological zones, where the deepwater plates of three huge structures relentlessly rub against one another—the intersection of the North American, South American and Caribbean tectonic plates. Below the ocean and the waters of the Caribbean, these plates consist of an oceanic crust some 3 to 6 miles thick, floating atop an adjacent mantle. Haiti also lies at the edge of the region known as the Bermuda Triangle, a vast area in the Caribbean subject to bizarre and unexplained disturbances.

This vast mass of underwater plates are in constant motion, rubbing against each other along lines analogous to cracks in a broken porcelain vase that has been reglued. The earth’s tectonic plates typically move at a rate 50 to 100 mm annually in relation to one another, and are the origin of earthquakes and of volcanoes. The regions of convergence of such plates are also areas where vast volumes of oil and gas can be pushed upwards from the Earth’s mantle. The geophysics surrounding the convergence of the three plates that run more or less directly beneath Port-au-Prince make the region prone to earthquakes such as the one that struck Haiti with devastating ferocity on January 12.


Feds to Eliminate One-Quarter of Greenhouse Gas Emissions in 10 Years

8:24 pm

WASHINGTON, DC , January 29, 2010 – President Barack Obama today announced that the federal government will reduce its greenhouse gas emissions by 28 percent by 2020.

MSU: Fiber harder to convert to fuel, worth effort

8:24 pm

MSU: Fiber harder to convert to fuel, worth effort EAST LANSING, Mich. – Michigan State university researchers say efficient biofuels made from plant fiber could be an important part of the fight against the greenhouse gases now causing our world to heat up.

New Coaxial Nanocables Show Enhanced Rate, Energy and Cycling Performance as Li-ion Electrode Materials; Yin-Yang Principle Extensible to Other Electrochemical Storage Devices

8:24 pm
Cntti02
Comparison of the rate performance of CNT@TiO2, TiO2-free CNT, and CNT-free TiO2 sample between voltage limits of 0.01-3 V. Shaded areas represent the capacity contribution from TiO2 or CNT in the nanocables. Credit: ACS, Cao et al. Click to enlarge.

Researchers in China and Germany have coated carbon nanotubes (CNT) with a nanoporous layer of TiO2 to create coaxial nanocables for use as electrode materials in Li-ion batteries (LIB). The CNT@TiO2 coaxial nanocables show excellent rate capability, energy and cycling performance compared with both pure CNT and pure TiO2 when used as anode materials for LIBs.

Both the specific capacity in the CNT core and that in the TiO2 sheath are much higher than that of the TiO2-free CNT and that of the CNT-free TiO2 sample, respectively. A paper on the work was published online 22 January in the ACS journal Chemistry of Materials.

While the carbon nanotubes assist the storage in TiO2 by providing electrons, the nanoporous TiO2 sheath assists the storage in the carbon nanotubes by enabling rapid access of Li+ from the liquid electrolyte. As the roles of ions and electrons are very different but complementing (compare acid-base activity
with redox activity), the mutually beneficial role of the two intimately connected components TiO2 (providing Li+ for CNT) and CNT (providing electrons for TiO2) finds a picturesque metaphor in the Chinese yin-yang principle.

—Cao et al.

Cntti02B
HRTEM images of the
nanocable. Credit: ACS, Cao et al. Click to enlarge.

A key problem in Li-battery research is guaranteeing sufficiently rapid transport of both ions and electrons, the researchers say, noting that only “a few exceptional materials” such as Ag2S provide fast ionic and electronic conduction even at room temperature that is sufficient to enable rapid chemical transport even in big crystals. Carbon provides sufficient electronic conductivity but lacks sufficient ion conductivity.

Among the many different approaches under investigation to addressing this problem is the use of carbon nanotubes (CNT).

CNT is also a fine Li-storage host as well as a fast Li insertion-extraction host at a low voltage, which makes it an attractive
anode material for lithium-ion batteries. However, the practical applications suffer from a high level of irreversibility (low columbic efficiency) and poor cycle life because of the pronounced surface reactions between
CNTs and electrolyte.

The basic point in our paper is the mutually beneficial,
i.e., symbiotic, role of the two intimately connected
phases CNT and TiO2. CNT is not just a metallizer for
the storage material TiO2, it efficiently stores Li as well. In
turn, for the storage of Li in CNT, the TiO2 proves
helpful, too. It allows for a rapid access of ions to the
CNT.

—Cao et al.

Among the results of the testing of the material, the researchers found a total reversible capacity (per total mass) of about
406 mAh g-1 in the voltage range of 0.01-3 V for the CNT@TiO2 nanocables under a current
density of 50 mAg-1; acid-treated CNTs showed a total reversible capacity of around 367 mAh g-1 under the same experimental
condition.

At a current density of as much as 3,000 mA g-1, CNT@TiO2 can still deliver a specific capacity of 244 mAh g-1 between the
voltage limits of 0.01 and 3 V. CNTs without TiO2 coating layers deliver 74 mAh g-1, and the CNT-free TiO2 has nearly no capacity under those conditions.

…our results demonstrate that very effective synergism could be introduced by using two-phase structures such as the coaxial nanocables reported here.
They can be used for designing superior electrode materials with improved performance in terms of power (rate), energy, and cycling behavior. The cable morphology also allows for a dense packing of electroactive materials.

…In the specific case of CNT@TiO2 core/porous-sheath coaxial nanocable, on one hand, the benefit of CNT for TiO2 storage consists in the electronic wiring principle (i.e., the CNT core providing
sufficient e- for the TiO2 sheath). On the other hand,
the benefit of nanoporous TiO2 for CNT is the almost
unperturbed Li+ supply for the CNT core, most probably
because of the porosity and the small thickness of the
passivation layer. It is the synergism of the two parts that
leads to a high, fast and stable lithium storage material.
The strategy is simple, yet very effective; because of its
versatility, it may also be extended to other electrode
materials for future electrochemical energy storage
devices (LIBs, supercapacitors, or hybrid) combining
high-power and high-energy densities.

—Cao et al.

Their work was supported by the National Natural Science Foundation of China, National Key Project on Basic Research, the Chinese Academy of Sciences, and the Max Planck Society in Germany.

Resources

  • Fei-Fei Cao, Yu-Guo Guo, Shu-Fa Zheng, Xing-Long Wu, Ling-Yan Jiang, Rong-Rong Bi, Li-Jun Wan and Joachim Maier (2010) Symbiotic Coaxial Nanocables: Facile Synthesis and an Efficient and Elegant Morphological Solution to the Lithium Storage Problem. Chem. Mater., Article ASAP doi: 10.1021/cm9036742

Brazil Ready to Cooperate With Iran on Sugarcane Ethanol, Other Technology

8:24 pm

FNA. In a meeting between Head of Iranian Industries Development and Renovation Organization (IDRO) Seyed Majid Hedayat and Deputy Brazilian Science and Technology Minister Czar Gadella in Tehran, Gadella said that Brazil is ready to cooperate with Iran in sugarcane ethanol and other fields of technology, including oil, gas, nanotechnology, microelectronics, information technology and biotechnology.

Hedayat said that IDRO is now working on projects for utilizing plant fuel, and added, “The existence of vast cane farms in southern (Iran), fuel, engine and vehicle research centers and auto-making companies indicates that the organization enjoys the required capability for research, production and supply of plant fuel.”

Brazil is the world’s second largest producer of ethanol fuel and the world’s largest exporter. Together, Brazil and the United States lead the industrial production of ethanol fuel, accounting together for 89% of the world’s production in 2008.

GDF Suez, Santos reach Australian LNG deal

12:03 pm

UPI has a report on yet another Australian LNG project, this one in the Timor sea – GDF Suez, Santos reach Australian LNG deal.

French energy giant GDF Suez signed an agreement with its Australian partners at Santos to develop three offshore gas fields in Australia, the company said.

GDF Suez announced a $200 million deal with Santos that concludes plans launched in August to develop its Bonaparte liquefied natural gas project. The integrated project envisions the construction of a floating liquefaction plant with a capacity to produce more than 2 million tons of LNG per year.

The project relies on gas resources from the Petrel, Tern and Frigate gas fields in the Bonaparte gas basin in the Timor Sea, which GDF Suez described as one of the richest gas regions in Australia.


The Low-Hanging Fruit of Energy Efficiency

12:03 pm

Kevin Drum has an article on profitable (for the buyer) forms of energy efficiency investment – Climate Change’s Low-Hanging Fruit.

If you don’t live in California, you might not have heard of Arthur Rosenfeld. But for the past four decades, he’s been the main inspiration behind a host of energy efficiency and conservation regulations that have made California the greenest state in the nation. He’s retiring from the California Energy Commission this week, and today the LA Times remembers his early battles :
New homes and buildings were required to be better insulated and fitted with energy-wise lighting, heating and cooling systems. Appliances had to be designed to use less power. Utilities were forced to motivate their customers to use less electricity.

….Not surprisingly, those rules were attacked by business groups as bureaucratic job killers. Rosenfeld, who received his doctorate from the University of Chicago, was called unqualified by critics at Pacific Gas & Electric Co., one of California’s largest utilities.

Yet these mandates have yielded about $30 billion annually in energy savings for California consumers. They’ve eliminated air pollution that’s the equivalent of taking 100 million cars off the roads. They have been copied by states and countries worldwide. California’s gains are so closely linked to Rosenfeld that they’ve been dubbed the Rosenfeld Effect in energy efficiency circles, where the 83-year-old has taken on rock star status.

Rosenfeld’s ideas, far from being job killers, have been a boon for California. We have plenty of problems here in the Golden State right now, but better energy efficiency isn’t one of them. In the end, Rosenfeld was right and his critics in the corporate world were wrong.

This reminds me of a current kerfuffle over energy efficiency on a national scale. McKinsey, the consultancy firm, has pressed the cause of energy efficiency for some time, and in 2007 they released a report that contained this now-famous chart (this is the 2009 version):

The point of the chart is simple: Some energy efficiency measures have a net cost and require fairly careful analysis to decide if they’re worthwhile. Those things are shown on the right side of the chart. But there are lots of efficiency measures that not only reduce greenhouse gas emissions but produce net cost savings at the same time. These are the low-hanging fruit of climate change, otherwise known as “no-brainers.” There are tremendous savings out there for the taking.

But there’s still opposition to this idea. A couple of weeks ago Ted Gayer of the Brookings Institution wrote that McKinsey’s conclusion “violates the basic principles of economics. If firms (or consumers) could reduce emissions at negative cost, then they would do so. To say otherwise is to say that they are willingly or ignorantly passing up profits.” But firms and consumers do pass up opportunities to save money. Maybe it’s through ignorance, maybe through laziness, maybe because of financing limitations. But there’s plainly friction in the real world that doesn’t always show up in simple Econ 101 models. A few days ago Brad Plumer linked to a Wall Street Journal report about an energy efficiency consultant, EnerNOC, that audited Morgan Stanley’s New York headquarters and immediately saved them a bundle of money…


China Leading Race to Make Clean Energy

12:03 pm

China vaulted past competitors in Denmark, Germany, Spain and the United States last year to become the world’s largest maker of wind turbines , and is poised to expand even further this year.

Domestic roof turbines proposal due

12:03 pm

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NT Tidal power project could run all homes

3:37 am

NT News has an article on interest in tidal power in the Northern Territory – Tidal power project could run all homes.

A COMPANY wants to build a multimillion-dollar tidal power project in the Top End. Territory-based Tenax says it could potentially generate enough electricity to supply 194,000 homes – more than exist in the NT. It has applied for an environmental assessment of the scheme at Clarence Strait at Glyde Point, 50km northeast of Darwin.

More than 450 generators would be installed across 1690ha of the seabed and connected to the NT’s electricity grid by 2km-long underground cables. Each generator would sit on a 14m x 21m x 3m-high concrete and steel base.

Clarence Strait was selected for two reasons:

* IT HAS the greatest tidal velocity near Darwin, with tidal movements of up to 5m; and
* IT HAS the minimum 20m depth needed for tidal power.


How will we recharge all the electric cars ?

3:37 am

The Economist has an overly-negative look at the issues involved in recharging electric cars in the US – How will we recharge all the electric cars?.

IN THE ten years since hybrid electric vehicles first hit the highways and byways of America, they have come to represent 2.5% of new car sales. Yet, in places like Los Angeles, the San Francisco Bay Area and Washington, DC, every other car seems to be a Toyota Prius. That is because hybrids like the Prius have sold overwhelmingly where well-heeled early adopters reside.

Expect the new generation of “Post-Prius” electrics—plug-in hybrids like the Chevrolet Volt from General Motors and those relying only on a battery such as the Nissan Leaf—to end up nosing around the same upscale neighbourhoods. With more than a dozen plug-in and pure-electric models arriving in showrooms over the next year or so, sales are expected to outstrip even those enjoyed by the Prius and other hybrids in their early days. A couple of million of the new electric vehicles could be bought by early adopters during the first few years.

That would be a problem. Unlike the Prius and its ilk—which use their petrol engines, along with energy recovered from braking, to recharge their batteries while motoring—plug-in hybrids and pure electrics have to be recharged direct from the grid. The popular assumption is that they will be plugged into a wall socket in the garage late at night, taking advantage of cheap off-peak power. Unfortunately, things are not that simple.

For a start, the new generation of electric vehicles are not glorified golf-carts, but cleaner and more frugal alternatives to today’s petrol-powered family cars. When fully charged, the Volt (to be called the Ampera in Europe) can travel 40 miles (64km) on electric power, enough for three out of four commuters in America to get to work and back without needing to burn a single drop of fuel. Beyond that range, a 1.4-litre engine kicks in to generate electricity and simultaneously propel the car and recharge its batteries.

The medium-sized hatchback Leaf can carry five adults 100 miles on a single charge. To go farther, Nissan has put its faith in a network of rapid-charging stations it is developing with partners. The Leaf is expected to cost $25,000-30,000, about the same as a comparable diesel-powered car. But the battery pack will have to be leased separately (for around $150 a month).

One thing the new plug-ins and pure electrics have in common is a beefy lithium-ion battery pack that needs a lot of heavy charging. At the very least, that involves installing 220-volt wiring in the home. Trying to recharge a modern electric car with a standard American 110-volt supply takes too long to be practical (up to 18 hours in the case of the Leaf).

Of course, if not fully charged at night it may have to be recharged during the day—when electricity rates can be up to five times more expensive. Average peak rates in America are 33 cents a kilowatt-hour compared with seven cents off-peak. Charging at the peak rate is equivalent to buying petrol at $3.63 a gallon (80 cents a litre), instead of 77 cents a gallon off-peak, reckons Southern California Edison, a utility based in the Los Angeles area. In America, peak-rate charging totally destroys any economic advantage an electric car may have. …

Much, of course, will depend on how quickly the new plug-ins and pure electrics become part of mainstream motoring. Generally speaking, it takes 15-20 years for a new technology to capture 10% of an established market, and a further 10-15 years for it to own 90%. That was the case when steam ships replaced clippers in the mid-19th century, and when petrol-engined taxis took over from horse-drawn cabs in the early 20th century. The same sort of lag occurred with the introduction in the 1970s of emission controls on cars. It takes years for the benefits of volume production to work their way through to the market, and for the supply chain to catch up.

If plug-in electrics follow a similar demand curve to other disruptive technologies, there could be 25m of them humming quietly around by 2025, and ten times that number by 2040. Hopefully, by then, the utilities will have learned to cope with recharging them.

The New York Times has an article on the forthcoming release of the plugin Toyota Prius – The Dawn of Plug-In Priuses and Smart Meters.

Toyota announced on Monday plans to begin selling “several tens of thousands” of plug-in versions of its popular Prius hybrid in 2012 2011, as Hiroko Tabuchi reports.

In another article in The New York Times today, Matthew L. Wald describes how the rollout of so-called smart meters – which are promoted by electric utilities as a way to save ratepayers money over the long term because they allow for variable electricity rates – is meeting resistance from skeptical consumers, who do not appreciate the meters’ up-front price tag.

In many ways, these articles are about pieces of the same thing — the “smart grid” envisioned for the future.

These two new technologies, plug-in cars and smart meters, are both critical components of the smart grid. In the future, large numbers of automobiles are expected to run on electricity and recharge from a home outlet during the night. (That is true not just of the plug-in Prius, but also of other electric vehicles in the pipeline, like the Chevrolet Volt.)

Smart meters are expected to help encourage consumers to charge their cars at night, because they allow utilities to offer lower rates for electricity at off-peak times. Far less electricity is used at night, when most people are sleeping, than during the day, so power plants have spare capacity to charge automobiles. However, under the current system, there is little incentive to charge automobiles at night because most utilities charge consumers a single rate that stays the same, daytime or nighttime.


Canada outlines greenhouse gas reduction targets in advance of UN deadline

3:37 am

The federal government has formally notified the United Nations that Canada will cut its carbon emissions by 17 per cent from 2005 levels over the next 10 years as part of the Copenhagen Accord on climate change, Environment Minister Jim Prentice announced Saturday.

ISU center gets grant for green job program

3:37 am

The U.S. Department of Labor grant will be funneled to ISU’s Energy Systems Technology and Education Center.

ClipperCreek Plug-in Charging Equipment CE-Certified for Deployment to Europe

3:37 am

ClipperCreek, Inc’s TS and CS product lines have been CE Certified and are ready for introduction into the European Union in 2010. The ClipperCreek EVSE (electric vehicle supply equipment) is also UL-Listed.

  • The TS line represents EVSEs specifically designed for use with the Tesla Roadster. The TS line is UL-listed to charge from 30 Amps to 100 Amps, accommodating power available at different charging locations.

  • The CS Line is for the home, office, fleet or public infrastructure. The CS line is also UL-listed to charge from 30 Amps to 100 Amps.

The company has begun shipping its TS-70 product to Europe with Tesla for use with the Tesla Roadster and plans to introduce its CS model for public infrastructure in the coming months.

ClipperCreek produced more than 2,500 chargers in 2009 and is the exclusive provider of EVSE chargers for BMW’s Mini-E and for Tesla Motors’ Level 2 EVSE charging stations. ClipperCreek also provides chargers to power Mercedes, GM and Nissan vehicles.

Study Finds Stratospheric Water Vapor Is An Important Driver of Decadal Global Surface Climate Change

3:37 am
Solomon2
Decadal warming rates arising from (i) greenhouse gases and aerosols alone (black); (ii) that obtained including
the stratospheric water decline after 2000 (red); and (iii) including both the stratospheric water vapor decline after 2000 and the increase in the 1980s and 1990s (cyan). Credit: Solomon et al., Science. Click to enlarge.

A 10% drop in stratospheric water vapor concentrations acted to slow the rate of increase in global surface temperature over 2000-2009 by about 25% compared to that which would have occurred due only to CO2 and other greenhouse gases, according to a new study by researchers from NOAA Earth System Research Laboratory; the University of Colorado, Boulder; and the University of Bern (Switzerland). Their paper was published online in the journal Science on 28 January.

Earlier observations from satellites and balloons suggest that stratospheric water vapor probably increased between 1980 and 2000, which would have enhanced the decadal rate of surface warming during the 1990s by about 30% compared to estimates ignoring this change, according to the authors.

These findings show that stratospheric water vapor represents an important driver of decadal global surface climate change.

—Solomon et al.

Over the last century, global average surface temperatures have warmed by about 0.75 °C (0.42 °C), with much of it occuring the last half. However, note the authors, the trend in global surface temperatures has been nearly flat since the late 1990s despite continuing increases in the forcing due to all the greenhouse gases.

Previous studies suggested that stratospheric water vapor might contribute significantly to climate change. The new study is the first to relate water vapor in the stratosphere to the specific variations in warming of the past few decades.

Solomon
Stratospheric water vapor and radiative processes. Source: NOAA. Click to enlarge.

The stratosphere is the region of the atmosphere from about eight to 30 miles above the Earth’s surface. Water vapor enters the stratosphere mainly as air rises in the tropics.

Stratospheric water vapor changes affect the fluxes of longwave (infrared) and—to a lesser extent—shortwave (solar)
radiation, and can thereby influence the temperature in the stratosphere and troposphere. In general, increases in stratospheric water vapor cool the stratosphere, but warm the troposphere; the reverse is true for decreases in stratospheric water vapor.

The researchers used data from the HALogen Occultation Experiment (HALOE) that flew on the Upper Atmosphere Research Satellite (UARS) from late 1991 through November 2005, with coverage from the troposphere to the stratosphere overs 65°S to 65 °N. Combined with two additional and independent sets of satellite data, the data provide evidence for “a sharp and persistent drop of about 0.4 parts per million by volume (ppmv)” in stratospheric water vapor after 2000.

Balloon data suggest a gradual mid-latitude increase in lower stratospheric water vapor of more than 1 ppmv from about 1980 to 2000. Other data also support increased in lower stratospheric water vapor during the 1990s of about 0.5 ppmv.

…recent observations have suggested a correlation of the post-2000 stratospheric water vapor decrease to sea surface temperature [SST] changes near the tropical warm pool region and associated cooling of the cold point that governs water vapor input to the stratosphere in the tropics. However, the relationship between SSTs in the warm pool region and stratospheric water vapor changes character (from negative to positive short-term correlations) from 1980–2009, suggesting that other processes may also be important, or that the correlation may be a transient feature
linked to the specific pattern of SSTs at a given time rather
than to the average warming of SSTs around the globe.

It is therefore not clear whether the stratospheric water vapor changes represent a feedback to global average climate change or a source of decadal variability. Current global climate models suggest that the water vapor feedback to global warming due to carbon dioxide increases is weak but these models do not fully resolve the tropopause or the cold point, nor do they completely represent the QBO, deep convective transport and its linkages to SSTs, or the impact of aerosol heating on water input to the stratosphere.

This work highlights the importance of stratospheric
water vapor for decadal rates of warming based directly upon
observations, illuminating the need for further observations
and a closer examination of the representation of stratospheric
water vapor changes in climate models aimed at interpreting
decadal changes and for future projections.

—Solomon et al.

Authors of the study are Susan Solomon, Karen Rosenlof, Robert Portmann, and John Daniel, all of the NOAA Earth System Research Laboratory (ESRL) in Boulder, Colo.; Sean Davis and Todd Sanford, NOAA/ESRL and the Cooperative Institute for Research in Environmental Sciences, University of Colorado; and Gian-Kasper Plattner, University of Bern, Switzerland.

Resources

  • Susan Solomon, Karen Rosenlof, Robert Portmann, John Daniel, Sean Davis, Todd Sanford, Gian-Kasper Plattner (2010) Contributions of Stratospheric Water Vapor to Decadal Changes in the Rate of Global Warming. Science Express doi: 10.1126/science.1182488

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